Accomplishments
Selective procedure for the conversion of alcohols into alkyl iodides with SO2 4 =ZrO2 and NaI at room temperature
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Category
Articles
Authors
Jitendra Satam & Radha Jayaram
Publisher
Elsevier B.v.
Publishing Date
01-Oct-2007
volume
9
Issue
6
Pages
1033-1039
- Abstract
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PDF Full Text
SO2 4 =ZrO2 was employed as a catalyst for the conversion of alcohols into the corresponding iodides using NaI in CH3CN at room temperature. Present procedure is found to be selective for the conversion of benzylic alcohols in the presence of saturated alcohols into benzylic iodides. The catalyst was characterized by XRD, FTIR, elemental analysis, BET surface area and TG–DTA techniques. This protocol provides a mild and efficient way for the one pot conversion of structurally diverse alcohols to their corresponding alkyl iodides with high selectivity.
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